Please use this identifier to cite or link to this item:
|Title:||The High-temperature Heat Capacity of LnPO4(Ln = La, Ce, Gd) by Drop Calorimetry|
|Authors:||POPA Karin; SEDMIDUBSKY D.; BENES O.; THIRIET Catherine; KONINGS RUDY|
|Citation:||JOURNAL OF CHEMICAL THERMODYNAMICS vol. 38 p. 825-829|
|Publisher:||ELSEVIER SCI LTD|
|Type:||Articles in periodicals and books|
|Abstract:||The high-temperature heat capacity of three lanthanide orthophosphates of monazite structure have been measured in the temperature range (450 to 1570) K. The data have been analysed in terms of a lattice term, represented by the 4f0 and 4f7 compounds LaPO4 and GdPO4, and an electronic term for CePO4. The calculated excess heat capacity thus obtained is in reasonable agreement with that calculated from the crystal field energies.|
|JRC Institute:||Nuclear Safety and Security|
Files in This Item:
There are no files associated with this item.
Items in repository are protected by copyright, with all rights reserved, unless otherwise indicated.