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|Title:||Thermodynamic Model of Solid Non-Stoichiometric Uranium Dioxide|
|Authors:||YAKUB E.; RONCHI Claudio; IOSILEVSKI I.|
|Citation:||JOURNAL OF PHYSICS-CONDENSED MATTER vol. 18 p. 1227-1248|
|Publisher:||IOP PUBLISHING LTD|
|Type:||Articles in periodicals and books|
|Abstract:||A thermodynamic description of the imperfect and nonstoichiometric ionic solid is obtained accounting for short- and long-ranged inter-ionic forces, as well as for formation of Frenkel defects. Both Coulomb and short-range interactions between defects are encompassed in a highly non-ideal ionic system where interactions of Frenkel defects are taken into account explicitly as short-ranged interactions of quasi-dipoles.|
|JRC Institute:||Nuclear Safety and Security|
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