Title: The Chemistry of the Phosphates of Barium and Tetravalent Cations in the 1:1 Stoichiometry
Authors: POPA KarinBREGIROUX DamienKONINGS RUDYGOUDER THOMASPOPA A.f.GEISLER T.RAISON PHILIPPE
Citation: JOURNAL OF SOLID STATE CHEMISTRY vol. 180 p. 2346-2355
Publisher: ACADEMIC PRESS INC ELSEVIER SCIENCE
Publication Year: 2007
JRC N°: JRC38232
URI: http://publications.jrc.ec.europa.eu/repository/handle/JRC38232
Type: Articles in Journals
Abstract: The chemistry of phosphates of barium and tetravalent cations [BaMIV(PO4)2] is reviewed. Such phosphates crystallise in the C2/m space group for MIV 1/4 Ti, Zr, Hf, Ge, Sn, and Mo, and in the P21/n space group for BaTh(PO4)2. The existence of BaMIV(PO4)2 in which MIV 1/4 Pb, Ce, and U is further evaluated. Several aspects, such as phase transitions in the compounds with yavapaiite structure, solid solutions of BaMIV(PO4)2 compounds and practical applications are briefly discussed.
JRC Institute:Institute for Transuranium Elements

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