Title: A TRLFS Study of Cm(III) Hydroxide Complexes in Alkaline CaCl2 Solutions
Authors: RABUNG T.ALTMAIER M.NECK V.FANGHAENEL Thomas
Citation: RADIOCHIMICA ACTA vol. 96 no. 9-11 p. 551-559
Publisher: OLDENBOURG VERLAG
Publication Year: 2008
JRC N°: JRC49446
ISSN: 0033-8230
URI: http://www.atypon-link.com/OLD/toc/ract/96/9-11
http://publications.jrc.ec.europa.eu/repository/handle/JRC49446
DOI: 10.1524/ract.2008.1536
Type: Contributions to Conferences
Abstract: Time-resolved laser fluorescence spectroscopy (TRLFS) is used to study Cm(III) solutions ([Cm]tot = 2×10-7 M) in 0.1¿3.5M CaCl2 at pHc ¿ 11.7 and in three sets of experiments at constant ionic strength (1.0, 2.5 and 3.5M CaCl2) with pHc varying from 10.8 to 11.9. The fluorescence spectra show Cm(III) emission bands in the range 605¿620 nm. Increasing the CaCl2 concentration strongly enhances the intensity of the observed bands.
JRC Institute:Institute for Transuranium Elements

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