Please use this identifier to cite or link to this item:
|Title:||Optimising BTP ligands by tuning their basicity|
|Authors:||TRUMM Sascha; WIPFF G.; GEIST A.; PANAK P.j.; FANGHAENEL Thomas|
|Citation:||RADIOCHIMICA ACTA vol. 99 no. 1 p. 13-16|
|Type:||Articles in periodicals and books|
|Abstract:||A novel approach for the optimisation of extractants for the actinide(III)/lanthanide(III) separation is presented. Two BTP ligands are synthesised carrying OMe or Cl moieties on the pyridine ring, thus altering the electronic structure of the aromatic system. The influence of functionalisation on the ligand basicity is determined both spectroscopically and by quantum chemical calculations. Furthermore, we show that both distribution ratios and separation factors for Am(III)/Eu(III) separation increase upon increase of ligand basicity|
|JRC Institute:||Institute for Transuranium Elements|
Files in This Item:
There are no files associated with this item.
Items in repository are protected by copyright, with all rights reserved, unless otherwise indicated.