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|Title:||Chemical interaction of yttrium aluminosilicate glass with CeO2, UO2 and PuO2 at high temperatures|
|Authors:||ROHBECK Nadia; MENNA MARIANO; SOMERS Joseph; COULAND Marc; HERRMANN M.; LIPPMANN W.|
|Citation:||NUCLEAR ENGINEERING AND DESIGN vol. 241 no. 8 p. 2775-2779|
|Publisher:||ELSEVIER SCIENCE SA|
|JRC Publication N°:||JRC61686|
|Type:||Articles in Journals|
|Abstract:||The thermal interaction of yttrium aluminosilicate glass with cerium, plutonium and uranium oxides at temperatures up to 1200°C has been studied by means of differential scanning calorimetry (DSC), X-ray diffraction (XRD), and secondary electron microscopy (SEM). The glass, a candidate for joining and sealing advanced fuel cladding materials, such as SiC, undergoes a recrystallisation process above 1000°C providing a mixture that exhibits two melting points at 1379 and 1410°C. Samples containing glass and actinide oxide mixtures did not form new phases, nor did the actinide oxides influence the recrystallisation behavior of the glass.|
|JRC Institute:||Institute for Transuranium Elements|
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