Title: Magnetic Memory Effect in a Transuranic Mononuclear Complex
Authors: MAGNANI NicolaAPOSTOLIDIS ChristosMORGENSTERN AlfredCOLINEAU EricGRIVEAU Jean-ChristopheBOLVIN HélèneWALTER OLAFCACIUFFO Roberto
Citation: Angewandte Chemie (German Edition) vol. 123 no. 7 p. 1734-1736
Publisher: Wiley-VCH Verlag GmbH&Co KGaA,
Publication Year: 2011
JRC Publication N°: JRC67703
ISSN: 0044-8249
URI: http://publications.jrc.ec.europa.eu/repository/handle/JRC67703
DOI: 10.1002/ange.201006619
Type: Articles in Journals
Abstract: Molecular nanomagnets that display magnetic bistability are the subject of intensive investigation due to their unique potential in ultrahigh-density memory components and spintronic devices.[1] So far, the best practical realization of such single-molecule magnets (SMMs) are polymetallic transition-metal complexes with strong intramolecular exchange coupling, giving rise to a high-spin ground state and negligible intercluster interactions.[2] However, 3d metals are restricted by their comparatively low anisotropy, and SMMs with better performance could be produced by exploiting the higher single-ion anisotropy typical of felectron ions.[3] This possibility has been practically demonstrated by Ishikawa et al., who discovered that mononuclear rare earth metal bis-phthalocyanine compounds (Pc2RE) display magnetic hysteresis under favorable conditions
JRC Institute:Institute for Transuranium Elements

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