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|Title:||Dioxin emisions from coal combustion in domestic stove: formation in the chimney and coal chlorine content influence|
|Authors:||PARADIZ Bostjan; DILARA Panagiota; UMLAUF Gunther; BAJSIĆ Ivan; BUTALA Vincenc|
|Citation:||THERMAL SCIENCE vol. 19 no. 1 p. 295-304|
|Publisher:||VINCA INST NUCLEAR SCI|
|Type:||Articles in periodicals and books|
|Abstract:||Combustion experiments conducted in domestic stove burning hard coal demonstrated a predominant influence of the coal chlorine content on the PCDD/F emissions, together with a pronounced effect of the flue gas temperature. PCDD/F concentrations of over 100 ng TEQ/m3, three orders of magnitude higher than in a modern waste incinerator, were measured in the flue gases of a domestic stove when combusting high chlorine coal (0.31 %). The PCDD/F concentrations in the flue gases dropped below 0,5 ng TEQ/m3, when low chlorine coal (0.07 %) was used. When low chlorine coal was impregnated with NaCl to obtain 0.38 % chlorine content, the emission of the PCDD/Fs increased by two orders of magnitude. Pronounced nonlinearity of the PCDD/F concentrations related to chlorine content in the coal was observed. The combustion of the high chlorine coal yielded PCDD/F concentrations in flue gases one order of magnitude lower in a fan cooled chimney when compared to an insulated one, thus indicating formation in the chimney. The influence of flue gas temperature on the PCDD/F emissions was less pronounced when burning low chlorine coal. The predominant pathway of the PCDD/F emissions is via flue gases, 99 % of the TEQ in the case of the high chlorine coal for insulated chimney.|
|JRC Directorate:||Sustainable Resources|
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