Title: A plutonium-based single-molecule magnet
Authors: MAGNANI NicolaCOLINEAU EricGRIVEAU Jean-ChristopheAPOSTOLIDIS ChristosWALTER OLAFCACIUFFO Roberto
Citation: CHEMICAL COMMUNICATIONS vol. 50 no. 60 p. 8171 - 8173
Publisher: ROYAL SOC CHEMISTRY
Publication Year: 2014
JRC N°: JRC89699
ISSN: 1359-7345
URI: http://pubs.rsc.org/en/content/articlelanding/2014/cc/c4cc03400g#!divAbstract
http://publications.jrc.ec.europa.eu/repository/handle/JRC89699
DOI: 10.1039/c4cc03400g
Type: Articles in periodicals and books
Abstract: The magnetic properties of the 5f5 [tris-(tri-1-pyrazolylborato)–plutonium(III)] complex have been investigated by ac susceptibility measurements, showing it to be the first plutonium single-molecule magnet; its magnetic relaxation slows down with decreasing temperature through a thermally activated mechanism followed by a quantum tunnelling regime below 5 K.
JRC Directorate:Nuclear Safety and Security

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