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Multi-functionalized nanoparticles are of great interest in biotechnology and biomedicine, especially for diagnostic and therapeutic purposes. However, at the moment the characterization of complex, multi-functional nanoparticles is still challenging and this hampers the development of advanced nanomaterials for biological applications. In this work, we have designed a model system consisting of gold nanoparticles functionalized with two differentially-terminated poly(ethylene oxide) ligands, providing both “stealth” properties and protein-binding capabilities to the nanoparticles. We use a combination of techniques (CLS, DLS, AF4, TEM, Z-potential, SDS-PAGE, and CD to: i) monitor and quantify the ratios of ligand molecules per nanoparticle; ii) determine the effect of coating density on nonspecific protein adsorption; iii) to assess the number and structure of the covalently-bound proteins. This article aims at comparing the complementary outcomes from typical and orthogonal techniques used on nanoparticle characterization by employing a versatile nanoparticle-ligands-biomolecule model system.
2018-07-12
ROYAL SOC CHEMISTRY
JRC109517
2040-3364,   
http://pubs.rsc.org/en/Content/ArticleLanding/2018/NR/C8NR00973B#!divAbstract,    https://publications.jrc.ec.europa.eu/repository/handle/JRC109517,   
10.1039/c8nr00973b,   
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