Study of the redistribution of U, Zr, Nb, Tc, Mo, Ru, Fe, Cr, and Ni between oxide and metallic phases in the matrix of a multiphase Chernobyl hot-particle extracted from a soil sample of the Western Plume

A “hot particle” found 6 km west of the Chernobyl nuclear power plant 4 years after the Chernobyl severe nuclear accident was analysed by scanning electron microscopy and electron probe micro-analysis. The matrix of the particle consists of relics of partly molten UO2 nuclear fuel and two different phases of solidified U–Zr–O melt (U0.77Zr0.23O2 and U0.67Zr0.33O2). The particle also contains a unique metallic inclusion of a size of 30×22 μm. The inclusion is non-homogeneous and in some parts shows a dendrite-like structure. It consists of about 38 wt.% Fe, about 10 wt.% U, Mo, and Nb, about 5 wt.% Ru, Zr, Ni, and Cr, and small amounts of Tc (2 wt.%) and Si (0.4 wt.%). The presence of partly molten nuclear fuel suggests a local temperature exceeding 2850 °C. The metallic inclusion most likely formed when steel, fuel, and cladding reacted together and molten steel incorporated U, Zr, Nb, Tc, Mo, and Ru from molten fuel and cladding during a very fast high-temperature process. Fast quenching of the metallic and the oxide melt left no time for Tc and Mo to evaporate. Molten Zr was partly oxidised and acted as a buffer for O which caused the reduction of a fraction of the U. The data of this study support the previously reported supercritical nature of the Chernobyl explosion.

POEML Philipp;  BURAKOV Boris E.; 

2018-12-06

WALTER DE GRUYTER GMBH

JRC110208

0033-8230 (online),   

https://publications.jrc.ec.europa.eu/repository/handle/JRC110208,   

10.1515/ract-2018-2957 (online),