Thermodynamic properties of Pb3U11O36

In order to progress in the development of Lead-cooled Fast Reactors, from the safety point of view it is essential to understand the chemical compatibility between liquid lead and uranium oxide. In the present work selected thermodynamic properties of Pb3U11O36, a possible ternary compound coming from fuel-coolant chemical interaction, were determined for the first time. Entropy at 298.15 K was obtained from low temperature heat capacity measurements using the Physical Property Measurement System (PPMS), while the high temperature heat capacity has been measured by a drop calorimeter. The experimental thermodynamic properties were compared with the values computed by means of DFT-GGA simulations, obtaining a very good agreement.

CERINI Marta;  BENES Ondrej;  POPA Karin;  MACERATA Elena;  GRIVEAU Jean-Christophe;  COLINEAU Eric;  MARIANI Mario;  KONINGS Rudy; 

2018-12-18

ELSEVIER SCIENCE BV

JRC111351

0022-3115 (online),   

https://publications.jrc.ec.europa.eu/repository/handle/JRC111351,   

10.1016/j.jnucmat.2018.07.042 (online),