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|Title:||Structural and thermodynamic study of Cs3Na(MoO4)2: Margin to the safe operation of sodium cooled fast reactors|
|Authors:||SMITH ANNA; KAURIC GUILLAUME; VAN EIJCK L.; GOUBITZ KEES; CLAVIER NICOLAS; WALLEZ G; KONINGS RUDY|
|Citation:||JOURNAL OF SOLID STATE CHEMISTRY vol. 269 p. 1-8|
|Publisher:||ACADEMIC PRESS INC ELSEVIER SCIENCE|
|Type:||Articles in periodicals and books|
|Abstract:||Neutron diffraction measurements of the double molybdate Cs3Na(MoO4)2 have been performed for the first time in this work and the crystal structure refined using the Rietveld method. The thermal expansion of this trigonal phase, in space group P m 3 1, measured using high temperature X-ray diffraction (XRD), remains moderate: α = 31·10 K a −6 −1 and α = 24·10 K c −6 −1 in the temperature range T = (298−723) K. The melting temperature of this compound has been determined at Tfus= (777 ± 5) K using Differential Scanning Calorimetry (DSC). No phase transition was detected, neither by DSC, nor by high temperature XRD or high temperature Raman spectroscopy, which disagrees with the literature data of Zolotova et al. (2016), who reported a reversible phase transition around 663 K. Finally, thermodynamic equilibrium calculations have been performed to assess the probability of formation of Cs3Na(MoO4)2 inside the fuel pin of a Sodium cooled Fast Reactor by reaction between the cesium molybdate phase Cs2MoO4, which forms at the pellet rim at high burnup, the fission product molybdenum (either as metallic or oxide phase), and the liquid sodium coolant in the accidental event of a breach of the stainless steel cladding and sodium ingress in the failed pin.|
|JRC Directorate:||Nuclear Safety and Security|
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