Product Analysis of the Gas Phase Reaction of beta-Caryophyllene with Ozone
The ketoaldehydes 3,3-dimethyl-gamma-methylene-2-(3-oxobutyl)-cyclobutanebutanal 1 and 3,3-dimethyl-gamma-oxo-2-(3-oxobutyl)-cyclobutanebutanal 2 have been identified as the main products of the reaction of beta-caryophyllene with ozone in the gas-phase. In addition forrmaldehyde and in minor amounts 9-methylene-4, 12, 12-trimethyl-5-oxabicyclo (8.2.0.04,5) dodecane 3 were formed too. Nature and yields of thesecarbonyl products are discussed in terms of oxidation mechanisms involving the gas phase reaction with ozone and OH radicals.
CALOGIROU Aggelos;
KOTZIAS Dimitrios;
1996-04-16
JRC12808
https://publications.jrc.ec.europa.eu/repository/handle/JRC12808,
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