Resonant inelastic x-ray scattering from U3O8 and UN

Resonant inelastic x-ray scattering (RIXS) using an incident energy tuned to the uranium N4,5 absorption edges is reported from epitaxial films of α-U3O8 and UN. Theory shows that for U3O8 the multiplets associated with a 5f 1 configuration with a ground state of 2F5/2 and the excited state of 2F7/2 are observed. However, the strong transition predicted at a transfer energy of 1.67 eV is not observed. We assume this is a consequence of the intermediate state lifetime broadening due to interaction with continuum states when the transferred energy exceeds the onset of the continuum in the presence of the core hole. This hypothesis is supported by the results obtained for the 5f-itinerant system UN, where no sharp transitions have been observed, although the broad scattering response centered at ∼ 1 eV is considered a signature of a predominantly 5f 3 configuration in this band-like semi-metallic system. These experiments and theory add important information on these materials, both of which have been investigated since the 1960s, as well as whether RIXS at the uranium N edge can become a valuable tool for actinide research.

BRIGHT Eleanor Lawrence;  LEI Xu;  HARDING Lottie M;  SPRINGELL R.;  WALTERS Andrew C.;  SUNDERMANN M.;  GARCIA-FERNANDEZ M.;  AGRESTINI Stefano;  CACIUFFO Roberto;  VAN DER LAAN Gerrit;  LANDER Gerard Heath; 

2023-03-27

IOP PUBLISHING LTD

JRC130053

0953-8984 (online),   

https://iopscience.iop.org/issue/0953-8984/35/17,    https://publications.jrc.ec.europa.eu/repository/handle/JRC130053,   

10.1088/1361-648X/acb8f4 (online),