Using the POD sampler for quantitative diffusive (passive) monitoring of volatile and very volatile organics in ambient air: Sampling rates and analytical performance

POD diffusive samplers loaded with Carbopack X and Carbograph 5TD were exposed to certified calibration mixtures containing a total of 110 different ozone precursor and air toxic compounds. Constant sampling rates were identified for 39 ozone precursors and 33 air toxics. As 9 of these compounds were included in both mixtures, this meant a total of 63 different volatile and very volatile compounds were sampled using the POD with overall expanded uncertainties below 30 % for the sampling rate associated with the whole range of sampling times from 2 to 24 h. A model has been developed and applied to estimate sampling rates, primarily for the more volatile and weakly adsorbed compounds, as a function of the collected amount of analyte and the exposure time. For an additional 9 ozone precursors on Carbopack X, and 11 air toxics on Carbograph 5TD, the expanded uncertainties of modelled sampling rates were reduced to below 30 % and have a significantly reduced uncertainty compared to those associated with an averaged sampling rate. The paper provides Freundlich’s isotherm parameters for the estimated (modelled) sampling rates and defines a pragmatic approach to their application. Finally, field measurement comparisons of POD samplers, pumped tube samplers and online gas chromatography (GC), for sampling periods of 3 and 7 days in a semi-rural background area, showed no significant differences between reported concentrations.

PEREZ BALLESTA Pascual;  BAU' Andrea;  FIELD Robert A;  WOOLFENDEN Elizabeth; 

2023-09-11

PERGAMON-ELSEVIER SCIENCE LTD

JRC132541

0160-4120 (online),   

www.sciencedirect.com/science/article/pii/S0160412023003926,    https://publications.jrc.ec.europa.eu/repository/handle/JRC132541,   

10.1016/j.envint.2023.108119 (online),