Some molecularly well-defined uranyl dicarboxylates are synthesized through the hydrothermal or solvothermal reaction of early dicarboxylic acids with uranyl nitrate, using either water or dimethylformamide (DMF) as the solvent. When these compounds are thermally decomposed in a spark plasma sintering (SPS) device, uranium carbides are formed. The resulting phases are determined by the uranium-to-carbon ratio of the precursor. In the case of the carbothermal reduction (CTR) of uranyl terephthalate, single-phase and nanocrystalline UC2 is obtained.
SURATEAU Adeline;
WALTER Olaf;
COLOGNA Marco;
POPA Karin;
2026-05-28
SPRINGER INTERNATIONAL PUBLISHING AG
JRC143636
2059-8521 (online),
https://link.springer.com/article/10.1557/s43580-026-01567-x,
https://publications.jrc.ec.europa.eu/repository/handle/JRC143636,
10.1557/s43580-026-01567-x (online),
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