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Derivatisation/Solid-Phase Microextraction Followed by Gas Chromatography-Mass Spectrometry for the Analysis of Phenoxy Acid Herbicides in Aqueous Samples.

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Solid-phase microextraction (SPME) coupled with high performance liquid chromatography (HPLC) was optimized for the combined analysis of the herbicides bentazone, 2,4-D, MCPA, dichlorprop, mecopro, atrazine and dinoseb in aqueous samples. The detection limits were in the low ug/L range for atrazine and the phenoxy acid herbicides, while detection limits below ug/L level were found for bentazone and dinoseb. By aqueous-phase derivatization with benzyl bromide followed by SPME-GC-MS analysis detection limits below ug/L level were obtained also for the phenoxy acid herbicides.
1997-08-18
JRC15328
https://publications.jrc.ec.europa.eu/repository/handle/JRC15328,   
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