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|Title:||Low Temperature Heat Capacity of PuPO4|
|Authors:||THIRIET Catherine; KONINGS RUDY; WASTIN FRANCK|
|Citation:||JOURNAL OF NUCLEAR MATERIALS vol. 344 p. 56-60|
|Type:||Articles in periodicals and books|
|Abstract:||PuPO4 was prepared successfully by coprecipitation and its heat capacity measured between 5 K and 300 K by a hybrid adiabatic relaxation calorimeter. The standard entropy S0 (298.15 K) of PuPO4 was derived and a semiempirical method was used to describe the total entropy as the sum of the lattice entropy Slat and the excess entropy Sexs as verified for the iso-electronic lanthanide orthophosphates. Thus the standard entropies of some actinide (III) orthophosphates were estimated.|
|JRC Directorate:||Nuclear Safety and Security|
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