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Low Temperature Heat Capacity of PuPO4

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PuPO4 was prepared successfully by coprecipitation and its heat capacity measured between 5 K and 300 K by a hybrid adiabatic relaxation calorimeter. The standard entropy S0 (298.15 K) of PuPO4 was derived and a semiempirical method was used to describe the total entropy as the sum of the lattice entropy Slat and the excess entropy Sexs as verified for the iso-electronic lanthanide orthophosphates. Thus the standard entropies of some actinide (III) orthophosphates were estimated.
2005-09-13
Elsevier B.V.
JRC30488
https://publications.jrc.ec.europa.eu/repository/handle/JRC30488,   
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