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The electronic and atomic structure of SrTiO3 crystals below the antiferrodistortive phase transition observed at 105 K is calculated using the hybrid B3PW functional as implemented in the ab initio CRYSTAL-2003 computer code. Such a combination of non-local exchange and correlation permits the calculation for the first time of the TiO6 octahedron rotational angle and the ratio c/a of tetragonal lattice constants in excellent agreement with experimental data.
2006-06-09
ELSEVIER SCI LTD
JRC33563
https://publications.jrc.ec.europa.eu/repository/handle/JRC33563,   
10.1088/0953-8984/18/20/009,   
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