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Electrochemical Behaviour of Americium Ions in LiCl-KCl Eutetic Melts

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This work presents a study on the electrochemical properties of AmCl3 in a molten LiClKCl eutectic, at a temperature range of 733-833 K. Transient electrochemical techniques, such as cyclic voltammetry and chronopotentiometry, on inert metallic tungsten working electrode have been used to investigate the reduction mechanism of Am3+ ions. The results show that Am3+ is reduced to Am metal by a two-step mechanism corresponding to the Am3+/Am2+ and Am2+/Am0 transitions.
2006-05-31
ELSEVIER SCI LTD
JRC33603
https://publications.jrc.ec.europa.eu/repository/handle/JRC33603,   
10.1016/j.electacta.2005.11.016,   
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