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Electronic Structure of the Americium Monopnictides - Ab Initio Calculations and Photoemission Experiments

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The f electrons in the actinide elements are less localized than in the corresponding lanthanide(4f) elements, yet there is a trend in increasing 5f localization with increase of atomic number. Americium, the element on the right-hand side of plutonium, "sits on the fence" of the 5f delocalization transition, i.e. the intriguing retraction of the 5f states from bonding which occurs between Pu and Am.
2006-10-19
Royal Society of Chemistry
JRC34685
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