The f electrons in the actinide elements are less localized than in the corresponding
lanthanide(4f) elements, yet there is a trend in increasing 5f localization with increase of atomic number. Americium, the element on the right-hand side of plutonium, "sits on the fence" of the 5f delocalization transition, i.e. the intriguing retraction of the 5f states from bonding which occurs between Pu and Am.
GOSH D.B.;
DE S.K.;
OPPENEER P.M.;
GOUDER Thomas;
BROOKS Michael;
WASTIN Franck;
HUBER Frank;
REBIZANT Jean;
2006-10-19
Royal Society of Chemistry
JRC34685
https://publications.jrc.ec.europa.eu/repository/handle/JRC34685,
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