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|Title:||The Chemistry of the Phosphates of Barium and Tetravalent Cations in the 1:1 Stoichiometry|
|Authors:||POPA Karin; BREGIROUX Damien; KONINGS RUDY; GOUDER THOMAS; POPA A.f.; GEISLER T.; RAISON PHILIPPE|
|Citation:||JOURNAL OF SOLID STATE CHEMISTRY vol. 180 p. 2346-2355|
|Publisher:||ACADEMIC PRESS INC ELSEVIER SCIENCE|
|Type:||Articles in periodicals and books|
|Abstract:||The chemistry of phosphates of barium and tetravalent cations [BaMIV(PO4)2] is reviewed. Such phosphates crystallise in the C2/m space group for MIV 1/4 Ti, Zr, Hf, Ge, Sn, and Mo, and in the P21/n space group for BaTh(PO4)2. The existence of BaMIV(PO4)2 in which MIV 1/4 Pb, Ce, and U is further evaluated. Several aspects, such as phase transitions in the compounds with yavapaiite structure, solid solutions of BaMIV(PO4)2 compounds and practical applications are briefly discussed.|
|JRC Directorate:||Nuclear Safety and Security|
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