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Improvement of Retention Capacity of ETS-10 for Uranyl Ions by Porosity Modification and their Immobilization into a Titanosilicate Matrix

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The retention capacity of ETS-10 titanosilicate for uranyl ions was improved by generation of additional intra-crystalline porosity with formation of an extended silica-rich surface area. Chemical bonds between uranyl groups and [SiO4] tetrahedra were found. By calcination at 800 °C, the uranium-loaded ETS-10 transforms into a inert titanosilicate matrix that encapsulates uranium
2008-08-07
ROYAL SOC CHEMISTRY
JRC47067
0959-9428,   
http://www.rsc.org/materials,    https://publications.jrc.ec.europa.eu/repository/handle/JRC47067,   
10.1039/b805049j,   
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