A TRLFS Study of Cm(III) Hydroxide Complexes in Alkaline CaCl2 Solutions
Time-resolved laser fluorescence spectroscopy (TRLFS) is used to study Cm(III) solutions ([Cm]tot = 2×10-7 M) in 0.1¿3.5M CaCl2 at pHc ¿ 11.7 and in three sets of experiments at constant ionic strength (1.0, 2.5 and 3.5M CaCl2) with pHc varying from 10.8 to 11.9. The fluorescence spectra show Cm(III) emission bands in the range 605¿620 nm. Increasing the CaCl2 concentration strongly enhances
the intensity of the observed bands.
RABUNG T.;
ALTMAIER M.;
NECK V.;
FANGHAENEL Thomas;
2008-12-16
OLDENBOURG VERLAG
JRC49446
0033-8230,
http://www.atypon-link.com/OLD/toc/ract/96/9-11,
https://publications.jrc.ec.europa.eu/repository/handle/JRC49446,
10.1524/ract.2008.1536,
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