Synthesis of Bimetallic Uranium and Neptunium Complexes of a Binucleating Macrocycle and Determination of the Solid-State Structure by Magnetic Analysis
Syntheses of the bimetallic uranium(III) and neptunium(III) complexes [(UI)2(L)], [(NpI)2(L)], and [{U(BH4)}2(L)] of the Schiff-base
pyrrole macrocycles L are described. In the absence of single-crystal structural data, fitting of the variable-temperature solid-state magnetic data allows the prediction of polymeric structures for these compounds in the solid state.
ARNOLD Polly L.;
POTTER Natalie A.;
MAGNANI Nicola;
APOSTOLIDIS Christos;
GRIVEAU Jean-Christophe;
COLINEAU Eric;
MORGENSTERN Alfred;
CACIUFFO Roberto;
LOVE Jason B.;
2010-07-13
ELSEVIER SCIENCE BV
JRC53275
1387-7003,
https://publications.jrc.ec.europa.eu/repository/handle/JRC53275,
10.1021/ic100374j,
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