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Determination of the NO3+NO2 - NO+O2+NO2 Rate Constant by Infrared Diode Laser and FT Spectroscopy

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THE RATE CONSTANT K1 AT 296 K FOR THE REACTION NO3+NO2 - NO+NO2+O2 HAS BEEN DETERMINED RELATIVE TO THE RATE CONSTANT K2, FOR THE REACTION NO3+NO - 2NO2 BY DIRECT MEASUREMENT OF NO AND NO2 IN A STEADY STATE SITUATION WHERE THE EFFECT OF THE THERMAL DECOMPOSITION OF NO3 WAS NEGLIGIBLE.
1995-03-15
JRC6062
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