catena-Poly[[tris(acetonitrile-kN)-praseodymium(III)tris(u-trifluoromethanesulfonato-k2O:O')]
The colourless complex catena-(tris((μ2-trifluoromethanesulfonato-O,O')-(acetonitrile-N))-\ praeseodym(iii))
crystallizes in the triclinic elemetary cell. The three triflate anions bridge via oxygen coordination between two
Pr atoms leading to a solid state structure with chains of the type [Pr(NCMe)3-μ2(OTf)3—Pr(NCMe)3-
μ2(OTf)3]n with the central metal atom in nine fold coordination of 6 O and 3 N atoms.
APOSTOLIDIS Christos;
WALTER Olaf;
2012-12-19
WILEY-BLACKWELL
JRC76892
1600-5368,
https://publications.jrc.ec.europa.eu/repository/handle/JRC76892,
10.1107/S1600536812049525,
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