Pressure-induced phase transitions in LnTe (Ln=La, Gd, Ho, Yb) and AmTe

The structural behaviour under compression of different lanthanide (La, Gd, Ho, Yb) and actinide (Am) monochalcogenides is studied by means of in situ high-pressure x-ray diffraction. All the investigated compounds crystallize at ambient conditions within a cubic (B1) NaCl-type structure but show different behaviours at high pressures. LaTe and AmTe undergo B1 to B2 (CsCl-type structure) phase transitions, starting at 9 GPa and 12 GPa, respectively. The high-pressure phase of AmTe exhibits an electronic transition, identified by an anomaly in the compression curve which is accompanied by a sample colour change. The other three monochalcogenides studied here show clear evidence of decomposition and amorphization under pressure and are, to the best of our knowledge, the first in the LnTe series to show a pressure-induced amorphization. The bulk moduli of all B1-type structure compounds are calculated using the third-order Birch–Murnaghan equation of state.

ZVORISTE-WALTERS Carmen;  HEATHMAN Stephen;  KLIMCZUK Tomasz; 

2013-07-31

IOP PUBLISHING LTD

JRC83087

0953-8984,   

http://dx.doi.org/10.1088/0953-8984/25/26/265401,    https://publications.jrc.ec.europa.eu/repository/handle/JRC83087,   

10.1088/0953-8984/25/26/265401,