Please use this identifier to cite or link to this item:
|Title:||Synthesis and crystal structure investigations of ternary oxides in the Na–Pu–O system|
|Authors:||BYKOV D.; RAISON Philippe; KONINGS Rudy; APOSTOLIDIS Christos; ORLOVA Maria|
|Citation:||JOURNAL OF NUCLEAR MATERIALS vol. 457 p. 54 - 62|
|Publisher:||ELSEVIER SCIENCE BV|
|Type:||Articles in periodicals and books|
|Abstract:||Ternary oxides of sodium and plutonium in oxidation states from +4 to +7 have been obtained by solid state reactions at elevated temperatures in pure argon or oxygen atmospheres. Sodium diplutonate was formed as a decomposition product of other plutonates at room temperature. The crystal structures of these compounds have been refined by the Rietveld method using conventional X-ray powder diffraction technique. The structural analogues were found among the families of complex oxides of alkali elements and cerium, ruthenium, antimony, uranium/neptunium and osmium. The new results were compared with the earlier known data for the system Na-Pu-O.|
|JRC Directorate:||Nuclear Safety and Security|
Files in This Item:
There are no files associated with this item.
Items in repository are protected by copyright, with all rights reserved, unless otherwise indicated.