A plutonium-based single-molecule magnet
The magnetic properties of the 5f5 [tris-(tri-1-pyrazolylborato)–plutonium(III)] complex have been investigated by ac susceptibility measurements, showing it to be the first plutonium single-molecule magnet; its magnetic relaxation slows down with decreasing temperature through a thermally activated mechanism followed by a quantum tunnelling regime below 5 K.
MAGNANI Nicola;
COLINEAU Eric;
GRIVEAU Jean-Christophe;
APOSTOLIDIS Christos;
WALTER Olaf;
CACIUFFO Roberto;
2014-08-06
ROYAL SOC CHEMISTRY
JRC89699
1359-7345,
http://pubs.rsc.org/en/content/articlelanding/2014/cc/c4cc03400g#!divAbstract,
https://publications.jrc.ec.europa.eu/repository/handle/JRC89699,
10.1039/c4cc03400g,
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