Evidence for lattice strain and non-ideal behaviour in the (La1-xEux)PO4 solid solution from X-ray diffraction and vibrational spectroscopy

GEISLER, T.; POPA, Karin; KONINGS, Rudy

doi:10.3389/feart.2016.00064

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Evidence for lattice strain and non-ideal behaviour in the (La1-xEux)PO4 solid solution from X-ray diffraction and vibrational spectroscopy

The monazite-type solid solution of LaPO4 and EuPO4 has been studied by X-ray and spectroscopic (infrared, Raman) techniques. The results all show deviations from ideal behaviour that have been interpreted in terms of lattice strains resulting from the ion size effects of substitution of La3+ by Eu3+.

GEISLER T.; POPA Karin; KONINGS Rudy;

2016-06-13

SPRINGER VERLAG

JRC99318

1863-4621,

https://publications.jrc.ec.europa.eu/repository/handle/JRC99318,

10.3389/feart.2016.00064,

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